Structure of hydrogen complexes in hydrates of the 1,2-naphthoquinone molecule

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Abstract

The question of the quantitative composition and structure of the formed hydrogen complexes of the 1,2-naphthoquinone molecule with water molecules in its hydration shell is considered. The problem was solved by comparing the calculated shifts of electronic transitions during the formation of hydrogen complexes with n = 5–13 water molecules with the experimental shifts of the absorption bands of 1,2-naphthoquinone in a water solution compared to a solution in n-hexane.

About the authors

S. N. Tseplina

Institute of Molecule and Crystal Physics, Ufa Federal Research Centre of the Russian Academy of Sciences

Email: SN_Tseplina@mail.ru
Ufa, 450075 Russia

E. E. Tseplin

Institute of Molecule and Crystal Physics, Ufa Federal Research Centre of the Russian Academy of Sciences

Ufa, 450075 Russia

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