Study of reaction of (E)-(3-aryl-3-oxoprop-1-en-1-yl)triphenylphosphonium bromides with 2-aminopyridine

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Resumo

(E)-(3-Aryl-3-oxoprop-1-en-1-yl)triphenylphosphoniumbromides react with 2-aminopyridine to form [(2-aryl-3-imidazo-[1,2-α-]pyridin-3-yl)methyl]triphenylphosphoniumbromides. An alternative scheme of the reactions is proposed, including an initial attack of the nucleophile on the carbonyl group.

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Sobre autores

R. Khachikyan

Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia

Autor responsável pela correspondência
Email: khachikyanraya@gmail.com
ORCID ID: 0009-0006-2014-7861
Armênia, prosp. Azatutyan, 26, Yerevan, 0014

K. Harutyunyan

Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia

Email: khachikyanraya@gmail.com
ORCID ID: 0000-0002-3274-1239
Armênia, prosp. Azatutyan, 26, Yerevan, 0014

A. Ayvazyan

Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia

Email: khachikyanraya@gmail.com
ORCID ID: 0000-0002-3224-0549
Armênia, prosp. Azatutyan, 26, Yerevan, 0014

Z. Hovakimyan

Institute of Organic Chemistry, Scientific and Technological Center of Organic and Pharmaceutical Chemistry, National Academy of Sciences of Armenia

Email: khachikyanraya@gmail.com
ORCID ID: 0009-0000-1604-5834
Rússia, prosp. Azatutyan, 26, Yerevan, 0014

Bibliografia

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2. Scheme

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3. Figure. Molecular structure of compound 2c according to X-ray diffraction data. Anisotropic thermal ellipsoids are shown with 50% probability.

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4. Figure

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