Ammonium salts as convenient ammonia surrogates in the willgerodt reaction

E. A. Kvetkin; Кветкин Евгений Александрович; A. V. Sokolov; Соколов Андрей Владимирович

doi:10.31857/S0514749225020128

Ammonium salts as convenient ammonia surrogates in the willgerodt reaction

作者: Kvetkin E.A.¹, Sokolov A.V.¹
隶属关系:
1. Samara State Medical University
期: 卷 61, 编号 2 (2025)
页面: 208-214
栏目: КРАТКОЕ СООБЩЕНИЕ
URL: https://hum-ecol.ru/0514-7492/article/view/684337
DOI: https://doi.org/10.31857/S0514749225020128
EDN: https://elibrary.ru/DHGUUT
ID: 684337

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详细

A novel solventless modification of the Willgerodt reaction is proposed. It employs elemental sulfur and ammonium salts as safe and convenient surrogates of ammonia on a solid carrier. The reaction involving combination of ammonium carbonate and aluminum oxide results in the amides of aryl acetic acids with yields from 48 to 85%.

关键词

Willgerodt reaction, aryl methyl ketones, amides of aryl acetic acids, elemental sulfur, ammonium salts, metal-organic frameworks

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作者简介

E. Kvetkin

Samara State Medical University

编辑信件的主要联系方式.
Email: eakvetkin@gmail.com
ORCID iD: 0009-0009-1014-0297
俄罗斯联邦, Chapayevskaya St., 89, Samara, 443099

A. Sokolov

Samara State Medical University

Email: eakvetkin@gmail.com
ORCID iD: 0000-0003-4965-3136
俄罗斯联邦, Chapayevskaya St., 89, Samara, 443099

参考

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